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Conformations of the Radical Anions from Dialkyl Maleates and Fumarates

✍ Scribed by Nelsen, S; Gillespie, J

Book ID
126273378
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
489 KB
Volume
40
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Radical anions of unsaturated esters. Th
Radical anions of unsaturated esters. The maleic-fumaric and phthalic systems
✍ S.F. Nelsen πŸ“‚ Article πŸ“… 1967 πŸ› Elsevier Science 🌐 French βš– 225 KB

The great stabilizing effect of conjugated carbonyl groups upon radical anions is well known. We here report e.s.r. spectra of unsaturated esters, which illustrate the effects of cis-trans isomerism on e.s.r. spectra.

Free radical initiation mechanisms in th
Free radical initiation mechanisms in the polymerisation of diethyl fumarate and diethyl maleate studied by the nitroxide trapping technique
✍ W. Ken Busfield; Ian D. Jenkins; Kirstin Heiland πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 580 KB

The radical trapping technique employing the stable nitroxide 1 as a scavenger has been used to study the reaction of t-butoxyl radicals with diethyl fumarate and with diethyl maleate. The major pathway with both monomers is hydrogen abstraction from the ester alkyl groups by t-butoxyl radicals. The