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Conformations of 2-Carboxy-1,4-butanedioic Acid as a Function of Ionization State in Dimethyl Sulfoxide

โœ Scribed by Nair, Gautham; Roberts, John D.


Book ID
127280288
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
50 KB
Volume
5
Category
Article
ISSN
1523-7060

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Conformational analyses of 2,3-dihydroxy
โœ Michael D. Drake; Alex K. Harsha; Sergei Terterov; John D. Roberts ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 246 KB

## Abstract Vicinal ^1^H๏ฃฟ^1^H coupling constants were used to determine the conformational preferences of 2,3โ€dihydroxypropanoic acid (1) (DLโ€glyceric acid) in various solvents and its different carboxyl ionization states. The stereospecific assignments of __J__~12~ and __J__~13~ were confirmed thr