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Conformations and Thermodynamic Properties of Sulfur Homocycles. 1. The S 5 , S 6 , S 7 , and S 8 Molecules

✍ Scribed by Cioslowski, Jerzy; Szarecka, Agnieszka; Moncrieff, David


Book ID
120294990
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
90 KB
Volume
105
Category
Article
ISSN
1089-5639

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Two stable solid phases with composition in the range from ( 45 to 48 ) moles per cent of \(\mathrm{S}\) exist for (nickel + sulfur): \(\mathrm{Ni}_{9} \mathrm{~S}_{8}\) which disproportionates to \(\mathrm{Ni}_{1-\delta} \mathrm{S}\) and \(\mathrm{Ni}_{7_{ \pm}} \mathrm{S}_{6}\) above \(T=\) \((709