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Conformations and strain energies of cyclic bisallenes based on ab initio molecular orbital calculations

✍ Scribed by Toshio Shimizu; Nobumasa Kamigata; Shigeru Ikuta


Book ID
114142021
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
658 KB
Volume
369
Category
Article
ISSN
0166-1280

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## Abstract Ab initio calculations on the conformations of several electron‐rich and electron‐poor alkenes 2, 8–15 were performed up to the MP2/6–31G^\*^/RHF/6–31G^\*^ level. It was proven that allylic 1,3‐strain can be traced back to steric interactions between the allylic center and the (Z) subst

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