Conformations and internal rotation of tri-isopropylmethane. Dynamic NMR and molecular mechanics studies
β Scribed by J.E Anderson; K.H Koon; J.E Parkin
- Book ID
- 108374403
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 645 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0040-4020
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Potential energy calculations (MM2), low-temperature 'H and I3C NMR spectra and 'H-'H COSY spectra are reported for four octane derivatives, the central portions of which constitute tetrasubstituted succinates. The existence of several conformers differing in stereochemistry in this central moiety i