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Conformational Switching of 3,7-Diacyl-3,7-diazabicyclo[3.3.1]nonanes by Metal Binding and by Solvent Changes

✍ Scribed by Vladimir A. Palyulin; Sergei V. Emets; Vyacheslav A. Chertkov; Christoph Kasper; Hans-Jörg Schneider

Book ID: 101281463
Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 250 KB
Volume: 1999
Category: Article
ISSN: 1434-193X
DOI: 10.1002/(sici)1099-0690(199912)1999:12<3479::aid-ejoc3479>3.0.co;2-h

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✦ Synopsis

Diacyl-3,7-diazabicyclo[3.3.1]

nonanes (3,7-diacylbispi-upon addition of LaCl 3 thus serving as models for potential allosteric systems. dines) can switch from antiparallel to parallel conformations the 13 C NMR spectrum. With rising temperature the ex- [a

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