Conformational study on the structures and energies of the weakly bound complexes of AlCl3 with diatomic molecules
β Scribed by Jimenez-Fabian, Issac ;Jalbout, Abraham ;Boutalib, Abderahim
- Book ID
- 111487997
- Publisher
- Walter de Gruyter GmbH
- Year
- 2007
- Tongue
- English
- Weight
- 201 KB
- Volume
- 5
- Category
- Article
- ISSN
- 2391-5420
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π SIMILAR VOLUMES
A theoretical research on the low-energy structures, binding energies, and Raman spectra of the (N 2 ) n (n ΒΌ 3-6) complexes has been systematically explored. Similar to the water trimer, the energetically lowest-lying structure of the nitrogen molecule trimer is a C 3h -symmetric cyclic structure.
## Abstract In an earlier publication (__J. Am. Chem. Soc.__ 2002, __124__, 7111) we showed that polymeric cationic [Ag(P~4~S~3~)~__n__~]^+^ complexes (__n__=1, 2) are accessible if partnered with a suitable weakly coordinating counterion of the type [Al(OR^F^)~4~]^β^ (OR^F^: polyβ or perfluorinate