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Conformational studies on phosphorus-containing macrocycles

✍ Scribed by R. Boese; R. Boetzel; G. Hägele

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
403 KB
Volume
32
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

H,H and P,H coupling constants and variable‐temperature ^1^H and ^13^C NMR spectra and ^13^C T~1~ values for some macrocyclic dithiophosphonic esters are presented to show that these compounds possess reduced flexibility in comparison with crown ethers. The NMR spectroscopic results are supported by an x‐ray structure which shows a highly strained ring system.

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