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Conformational studies by nuclear magnetic resonance—V:13C spectra and structural problems of enamino carbonyl compounds

✍ Scribed by Lech Kozerski; Janusz Dabrowski


Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
401 KB
Volume
5
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

A ^13^C magnetic resonance investigation of 22 compounds of the general formula OC^1^(R^1^)C^2^(R^2^)C^3^(R^3^) NR^4^R^4′^ has been carried out in order to confirm the conformational assignments estimated previously by PMR and IR spectroscopy. The effects of nonplanarity and hindered rotation have been discussed based on chemical shifts and shapes of the C^1^, C^2^ and C^3^ signals.


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