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Conformational Studies by Dynamic NMR. 67. 1 Ring Inversion, in Solution and in the Solid, of the Silane Analogue of Permethylcyclohexane: Dodecamethylcyclohexasilane

โœ Scribed by Casarini, Daniele; Lunazzi, Lodovico; Mazzanti, Andrea

Book ID
126829601
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
70 KB
Volume
63
Category
Article
ISSN
0022-3263

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โœ Constantinos Sakarellos; Ioannis P. Gerothanassis; Nicolaos Birlirakis; Theodoro ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 696 KB

## Synopsis The synthesis of Leu-enkephalin selectively l70-enriched in Gly' and Gly3 is reported. The 170-nm chemical shifts of Leu5]-and [170-Gly3, Le~~l-enkephalins in H,O are almost identical and independent of the pH. Since hydrogen bonding is the dominant factor governing the chemical shifts