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Conformational Stereochemistry of the HERON Amide, N -Methoxy- N -dimethylaminoformamide: A Theoretical Study

✍ Scribed by Glover, Stephen A.; Rauk, Arvi


Book ID
127194073
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
206 KB
Volume
64
Category
Article
ISSN
0022-3263

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HERON rearrangement of N,Nβ€²-diacyl-N,Nβ€²-
✍ Stephen A. Glover; Guoning Mo; Arvi Rauk πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 909 KB

Ab initio calculations at the B3LYP/6-31G\* level on N-methoxy-N-dimethylaminoformamide and its rearrangement to methyl formate and 1,l-dimethyldiazene through the HERON reaction, have been carried out in conjunction with an experimental study of the HERON reactions of N,N'-diacyl-N,N'-dialkoxyhydra