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Conformational stability, r0 structural parameters, barriers to internal rotation, vibrational spectra and ab initio calculations of c-C3H5SiH2CH3

โœ Scribed by James R. Durig; Savitha S. Panikar; Gamil A. Guirgis; Todor K. Gounev; Rachel M. Ward; Rebecca A. Peebles; Sean A. Peebles; Richard J. Liberatore; Stephen Bell; Charles J. Wurrey


Book ID
108213032
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
379 KB
Volume
923
Category
Article
ISSN
0022-2860

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The infrared (3500-300 cm ร€1 ) and/or Raman (3500-50 cm ร€1 ) spectra of gaseous, liquid and solid of methylisocyanate, CH 3 NCO, have been recorded. Fine structures of the nearly free internal rotation of the methyl rotor has been observed for the pseudodegenerate CH 3 stretch and deformation from w