Conformational Stability of Chloromethyl Silyl Chloride from Temperature-Dependent FT-IR Spectra of Krypton Solutions
โ Scribed by Gamil A. Guirgis; Chunhua Pan; Shiyu Shen; James R. Durig
- Book ID
- 110309588
- Publisher
- Springer
- Year
- 2001
- Tongue
- English
- Weight
- 186 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1040-0400
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๐ SIMILAR VOLUMES
Variable temperature (2105 to 2150 8C) studies of the infrared spectra (3500 -400 cm 21 ) of 1,1-dimethylhydrazine, (CH 3 ) 2 NNH 2 , in liquid krypton have been carried out. No convincing spectral evidence could be found for the trans conformer which is expected to be at least 600 cm 21 less stable
The infrared spectra (3500 to 40 cm ร1 ) of gaseous and solid and the Raman spectra (3500 to 30 cm ร1 ) of liquid and solid 1-fluorosilacyclobutane, c-C 3 H 6 SiFH, have been obtained. Both the axial and equatorial conformers with respect to the fluorine atom have been identified in the fluid phases