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Conformational Stability of Chloromethyl Silyl Chloride from Temperature-Dependent FT-IR Spectra of Krypton Solutions

โœ Scribed by Gamil A. Guirgis; Chunhua Pan; Shiyu Shen; James R. Durig


Book ID
110309588
Publisher
Springer
Year
2001
Tongue
English
Weight
186 KB
Volume
12
Category
Article
ISSN
1040-0400

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๐Ÿ“œ SIMILAR VOLUMES


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Variable temperature (2105 to 2150 8C) studies of the infrared spectra (3500 -400 cm 21 ) of 1,1-dimethylhydrazine, (CH 3 ) 2 NNH 2 , in liquid krypton have been carried out. No convincing spectral evidence could be found for the trans conformer which is expected to be at least 600 cm 21 less stable

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The infrared spectra (3500 to 40 cm ร€1 ) of gaseous and solid and the Raman spectra (3500 to 30 cm ร€1 ) of liquid and solid 1-fluorosilacyclobutane, c-C 3 H 6 SiFH, have been obtained. Both the axial and equatorial conformers with respect to the fluorine atom have been identified in the fluid phases