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Conformational properties of poly(p-Phenylene vinylene)

✍ Scribed by Petr Toman; Lubomír Skála; Josef Pospíšil

Book ID
110405414
Publisher
Springer
Year
1998
Tongue
English
Weight
271 KB
Volume
48
Category
Article
ISSN
0011-4626

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We investigate the quasi-particle conformational defects (excitons, polarons and bipolarons) in phenylene vinylene oligomers (PVOs) consisting of up to 12 repeat units. The conformations are determined by minimisation of the total Hartree-Fock energy calculated at 3-21G level. The Hartree-Fock calcu

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A new p-phenylene-vinylene-thiophene-based siloxane block copolymer has been synthesized. The copolymer consists of alternating rigid and flexible blocks. The rigid blocks are composed of phenylene-vinylene-thiophene-based units, and the flexible blocks are derived from 1,3-dialkyldisiloxane units.