Conformational Preferences of N -Acetyl- l -leucine- N ‘-methylamide. Gas-Phase and Solution Calculations on the Model Dipeptide
✍ Scribed by Masman, Marcelo F.; Lovas, Sándor; Murphy, Richard F.; Enriz, Ricardo D.; Rodríguez, Ana M.
- Book ID
- 126087928
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 734 KB
- Volume
- 111
- Category
- Article
- ISSN
- 1089-5639
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## Abstract We have examined the NH stretching frequencies of __N__‐acetyl‐__N′__‐methyl‐L‐alanineamide (blocked Ala), __N__‐acetyl‐__N′__‐methylglycineamide (block Gly), and __N__‐acetyl‐__N′__‐methyl‐L‐leucineamide (blocked Leu) in chloroform using irspectroscopy. Their spectrum of blocked Leu in
## Abstract φ – ψ maps have been calculated by the MM2(87) potential for the __N__^α^‐acetyl derivatives of Gly, Ala, Val, and Tle methylamides and their __N__^α^‐methyl substituted derivatives to interpret the ^1^H NMR and CD spectra of these compounds. From the critical examination of the availab