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Conformational Preferences of cis -1,3-Cyclopentanedicarboxylic Acid and Its Salts by 1 H NMR Spectroscopy: Energetics of Intramolecular Hydrogen Bonds in DMSO

✍ Scribed by Emenike, Bright U.; Carroll, William R.; Roberts, John D.


Book ID
119947924
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
309 KB
Volume
78
Category
Article
ISSN
0022-3263

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The 'H-nmr studies were extensively carried out to elucidate preferred conformations of dipeptides CH,C\*O-X-NHCH,, with X = Abu, oval, and Val in various solvents. The vicinal 'H--'H coupling constants for the NH-CnH moiety and those around the C"-Cp bond in the articulated side chain provided the