Conformational Mobility of Substituted 2-Methoxychalcones under the Action of Lanthanide Shift Reagents
โ Scribed by A. V. Turov; S. P. Bondarenko; A. A. Tkachuk; V. P. Khilya
- Book ID
- 106523357
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2005
- Tongue
- English
- Weight
- 185 KB
- Volume
- 41
- Category
- Article
- ISSN
- 1070-4280
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complexation of five meaningful series of pyridines bearing substituents in positions was investigated by 'H-NMR with Eu(dpm)) and m(fod)y. The former TSR leads to higher MIS values than the latter when small a-substituents ere present, but
## Abstract The position of the lanthanide atom calculated from the pseudocontact shift equation was studied for 2โadamantanol and 2โmethylโ, 2โethylโ, 2โpropylโ, 2โbutylโ2โadamantanol. The possible methods of calculation considering rotation of the methyl group were ascertained in the case of 2โme