Conformational Mobility and Optical Rotation Effects of Aromatic Nuclei 1
✍ Scribed by Brewster, James H.; Buta, J. George
- Book ID
- 127368413
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 966 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The vapor‐phase optical rotation (or circular birefringence) of (__S__)‐1,2‐epoxybutane, (__S__)‐epichlorohydrin, and (__S__)‐epifluorohydrin has been measured at the nonresonant excitation wavelengths of 355 nm and 633 nm by means of Cavity Ring‐Down Polarimetry (CRDP). Complementary s
## Abstract A computational investigation of the optical rotatory power of __cis__ and __trans__ 2‐methyl‐5‐oxo‐tetrahydro‐3‐furancarboxylic acids and the corresponding methyl and ethyl esters is presented. Solvent effects on both the conformational space and the rotatory power are analyzed by comp
A chiroptical method of conformational analysis is applied to linear ( 1 + 3 ) -p-D-glucans and the dimeric analogues pand a-laminaribioside. The method is based on a recently developed semiempirical calculational model for saccharide optical activity. We conclude that disaccharide conformational en