Conformational Isomerism and Chlorotropy Mechanisms of Chloromethyl- and Trichloromethyldichlorophosphines
β Scribed by E. A. Romanenko; A. M. Nesterenko
- Book ID
- 110308200
- Publisher
- Springer
- Year
- 2001
- Tongue
- English
- Weight
- 66 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-5760
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## Abstract 2β(Chloromethyl)oxetane was prepared in 8% overall yield from 2βpropenβ1βol by protection of the alcohol with dihydropyran, epoxidation, ring expansion with dimethylsulfoxonium methylide, acid deprotection, and chlorination with triphenylphosphine in CCl~4~. 3β(Chloromethyl)oxetane was
## Ah&act--Infrared and Raman spectra of liquid and solid (chloromethyl)thiirane (3chloropropylene sulfide), along with the infrared and microwave spectra of the vapor, have been recorded. The vibrational spectra are consistent with the existence of at least two conformations. Unlike the situation