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Conformational equilibria in six-membered rings

โœ Scribed by Hermann M. Niemeyer

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
233 KB
Volume
57
Category
Article
ISSN
0022-2860

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๐Ÿ“œ SIMILAR VOLUMES

The conformation of non-aromatic ring co
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Recently, the conformational equilibria in some vicinal dihslcgencalkanes (see Fig.1) have been studied (2,3) by means of dipole moments in benzene and in carbon tetrachlcride solution at 25'c. From the experimental equilibrium constants the gauche interaction FIG.l. The conformers of vicinal dihalc

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It is of interest to consider the restraints imposed on the stable conformation of a six-membered ring by the presence of a planar group forming part of the ring and how the specific dimensions of the planar group may determine the conformational selection. The principal groups for which evidence i