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Conformational dynamics and the rotational isomeric state model

✍ Scribed by Worth E. Vaughan

Publisher
Elsevier Science
Year
1978
Weight
748 KB
Volume
13
Category
Article
ISSN
0378-4487

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✦ Synopsis

The dynamics of diffusion of a system described by a one-dimensional orientations in the computation of the mean dipole moment. This systematic error in the calculation of a static property increases as the barriers decrease.

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Steady-state fluorescence was used to measure the ratio of emission intensities, denoted I D /I M , for excited state complexes and excited monomers of five trichromophoric compounds, 2-naphthyl-COO-(CH 2 ) m -OOC-2,6-dinaphthyl-COO-(CH 2 ) m -OOC-2-naphthyl, m Ο­ 2-6. The linear aliphatic alcohols H