Conformational Control of Excited-State Dynamics in Highly Distorted Ru(II) Polypyridyl Complexes
β Scribed by McFarland, Sherri A.; Magde, Douglas; Finney, Nathaniel S.
- Book ID
- 126259169
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 274 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
The dynamics of benzene(NH3) n heteroclusters is studied with 170 fs laser pulses in a molecular beam. The clusters were excited to about 6.2 eV, i.e. above the S 2 state of bare benzene. By varying the probe energy (3.1 and 4.65 eV) we examined the dynamics of internal conversion and their dependen
The temperature dependence of photosubstihrtion for several polypyridine ruthenium@) complexes has been examined. In contrast to the parent tris-bipyridineruthenium(lI), little temperature dependence is observed. These results. combined with quenchmg data, provide kinetic details on the intermediate