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Conformational characterisation of valinomycin complexation with barium salts—A nuclear magnetic resonance spectroscopic study

✍ Scribed by S. Devarajan; K. R. K. Easwaran

Book ID
112828809
Publisher
Indian Academy of Sciences
Year
1984
Tongue
English
Weight
654 KB
Volume
6
Category
Article
ISSN
0250-5991

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## Abstract The 251 MHz ^1^H and the natural abundance 63.1 MHz ^13^C NMR spectra of 1,3‐dioxepane (1) and 4,4,7,7‐tetramethyl‐1,3‐dioxepane (2) have been investigated over the temperature range of 5 to −180 °C. While the spectra of 1 show no dynamic NMR effect, compound 2 exists in solution as a 1