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Conformational changes by ring puckering and inversion in 1,3,2-dioxaphospholene

✍ Scribed by M.Alcolea Palafox; Vladimir I. Perevozchikov; James E. Boggs; Leonid S. Khaikin


Book ID
113257479
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
559 KB
Volume
228
Category
Article
ISSN
0166-1280

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Thetitle compound 3 wasprepared via a cyclization reactionbetween twoknown precursors.It is confmnedthat the inversion process of the 1,3-bridged ring in the 2,17dithia[3.3](2,2') biphenyleno(l ,3)cyclophane systemwasrestricted with a conforrnational enemy barrier of >64kJmol-'. Theadopted rigidconf