The known tendency of halogen or alkoxyl groups on C-l in a pyranose system to adopt an axial conformation is generally designated as the anomeric effect. This effect plays an important and frequently discussed role in the field of conformational analysis of carbohydrates and related acetals '. The
✦ LIBER ✦
Conformational calculations for the α and β anomer of 2,3,4-tri-O-acetyl-d-arabinopyranosyl azide
✍ Scribed by Marianna Strumpel; Peter Luger
- Book ID
- 107725707
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 423 KB
- Volume
- 180
- Category
- Article
- ISSN
- 0008-6215
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The crystal and molecular structure of Z-phenyl-(3,4,6- (2) has been determined. The compound crystallises in the space group P2,2,2 with lattice constants 13.4160(3), 37.4931( 14)) and 7.7886( 1) A, and Z = 8. Direct methods were used in the solution. Least squares refined the model with 3213 obse