Matrix isolation-supersonic jet infrared
Matrix isolation-supersonic jet infrared spectroscopy: conformational cooling in trimethyl phosphate
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V. Vidya; K. Sankaran; K.S. Viswanathan
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Article
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1996
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Elsevier Science
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English
β 371 KB
A supersonic jet source has been coupled to a matrix isolation set-up to obtain conformational cooling in organic phosphates. Infrared spectra of trimethyl phosphate (TMP) trapped in a nitrogen matrix using supersonic jet sampling, indicated that the higher-energy conformer of TMP was significantly