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Conformational behaviour of trimethyl phosphate studied by infrared spectroscopy

✍ Scribed by Roman Streck; Austin J. Barnes; Wouter A. Herrebout; Benjamin J. van der Veken


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
756 KB
Volume
376
Category
Article
ISSN
0022-2860

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Matrix isolation-supersonic jet infrared
✍ V. Vidya; K. Sankaran; K.S. Viswanathan πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 371 KB

A supersonic jet source has been coupled to a matrix isolation set-up to obtain conformational cooling in organic phosphates. Infrared spectra of trimethyl phosphate (TMP) trapped in a nitrogen matrix using supersonic jet sampling, indicated that the higher-energy conformer of TMP was significantly