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Conformational behavior of 1,2-dibromo-2-methylbutane

✍ Scribed by G.A. Crowder

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 135 KB
Volume: 216
Category: Article
ISSN: 0022-2860
DOI: 10.1016/0022-2860(90)80341-g

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Rate constants, k, were determined for the solvolytic reactions of 2-bromo-2-methylbutane, 2-chloro-2methylbutane and 3-chloro-3-methylpentane in 10 pure diols at 298.15 K. The Gibbs energies of activation were calculated in order to study the influence of the solvent and to provide mechanistic info