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Conformational and vibrational analysis of butyronitrile

✍ Scribed by G.A. Crowder


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
401 KB
Volume
158
Category
Article
ISSN
0022-2860

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Conformational Analysis of Bicyclopropyl
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On reaction with N,N-dichloro-t-butylamine or -cyclohexylamine in benzene at 0 "C, nickel tetracarbonyl evolves three moles of carbon monoxide per mole. A colorless precipitate ( I ) is formed that has a Ni:N ratio of 1 : 1 and is insoluble in the usual solvents. 2 RNClz + 2 Ni(CO)4 + 2 [RNClzNi(CO)