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Conformational and substituent effects on spin distributions in porphyrin cation radicals

✍ Scribed by Renner, M. W.; Cheng, R. J.; Chang, C. K.; Fajer, Jack.


Book ID
120560655
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
511 KB
Volume
94
Category
Article
ISSN
0022-3654

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## Abstract A series of 7‐^13^C‐labeled __o__‐substituted toluene derivatives and carboxyl‐^13^C‐isocrotonic and crotonic acid were synthesized and studied by ^13^C NMR spectroscopy to obtain ^13^C^13^C spin‐spin coupling constants involving the labeled carbon. The __cis__ ^3^__J__(CC) values were