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Conformational and structural studies of 2-fluoroethylamine from temperature dependent FT-IR spectra of krypton and xenon solutions and ab initio calculations

โœ Scribed by James R. Durig; Arindam Ganguly; Chao Zheng; G.A. Gurigis; W.A. Herrebout; B.J. van der Veken; Todor K. Gounev


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
687 KB
Volume
968
Category
Article
ISSN
0022-2860

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Variable temperature (2105 to 2150 8C) studies of the infrared spectra (3500 -400 cm 21 ) of 1,1-dimethylhydrazine, (CH 3 ) 2 NNH 2 , in liquid krypton have been carried out. No convincing spectral evidence could be found for the trans conformer which is expected to be at least 600 cm 21 less stable