Conformational analysis—XXI : H NMR Conformational Study of Alkyl-Substituted 2-Oxo-1,3,2-Dioxathianes
✍ Scribed by Tertu Virtanen; Hannu Nikander; Kalevi Pihlaja; Erkki Rahkamaa
- Book ID
- 107857276
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 919 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4020
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I7O NMR chemical shifts of 2-oxo-1,3,2-dioxathiane and 13 of its methyl-substituted derivatives are reported. The chemical shifts depend strongly on temperature and to a much smaller extent on concentration. As a whole, however, they strongly support the predominance of chair conformations in these
## Abstract Seven isomeric 4,5,6‐trimethyl‐2‐oxo‐1,3,2‐dioxathians, __cis__‐4‐__trans__‐6‐dimethyl‐__r__‐2‐oxo‐1,3,2‐dioxathian and two isomeric 4,5,5,6‐tetramethyl‐2‐oxo‐1,3,2‐dioxathians were prepared and their ^1^H n.m.r. spectra analysed. The values of the vicinal coupling constants reported ea