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Conformational analysis. XXVII. Solvent effects in conformational equilibriums of heterosubstituted 1,3-dioxanes

โœ Scribed by Eliel, Ernest L.; Hofer, Otmar.


Book ID
118118214
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
596 KB
Volume
95
Category
Article
ISSN
0002-7863

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Solvent effects in conformational analys
โœ W.F. Trager; B.J. Nist; A.C. Hultric ๐Ÿ“‚ Article ๐Ÿ“… 1965 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 296 KB

We have observed that the PHI7 spectrum of cls-1,4-cyclohexanedlol obtained In pyrldlne Is very dlfferent from that obtalned In D2D. The slgnal of the methylens protons glve a complex rmltlplat spread over more than 50 c/s In pyrldlne but glve a synsnetrlcal trlplet with separation of 2.5 c/s and ha