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Conformational Analysis. VIII. The Conformational Equilibrium Constant of the Carbethoxyl Group 1

โœ Scribed by Eliel, Ernest L.; Haubenstock, H.; Acharya, R. V.

Book ID
127145479
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
568 KB
Volume
83
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

The conformational equilibrium constant
The conformational equilibrium constant of divalent sulfur
โœ Ernest L. Eliel; Louis A. Pilato ๐Ÿ“‚ Article ๐Ÿ“… 1962 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 156 KB

IN the previous letter,' a conformational free energy difference2 of 0.8 kcal/mole was reported for the -SC6H5 group. The small magnitude of this difference agrees with the finding of Chiurdoglu and coworkers3 for -SH based on infrared study and is also in line with findings for other single atoms,

The conformational equilibrium of the am
The conformational equilibrium of the amino group
โœ E.L. Eliel; E.W. Della; T.H. Williams ๐Ÿ“‚ Article ๐Ÿ“… 1963 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 218 KB

Williams of Notre Dame, AMONG the numerous conformational equilibrium values reported in the literature 1,2 that of the amino group is conspicuously missing. Tich;, Jon;; and Sicher3 some years ago determined pK data which indicate a qualitatively that the -dG value for the equilibrium is comparable