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Conformational Analysis of the Molecular Complexes of Sodium with Methanol and 1,2-Ethanediol: Photoionization and ab Initio Molecular Orbital Studies

✍ Scribed by Yeh, T.-S.; Su, T.-M.


Book ID
121413501
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
82 KB
Volume
103
Category
Article
ISSN
1089-5639

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Among some 2-substituted 4H-1,3,2-benzodioxaphosphorin 2-sulfides, the 2-OMe derivative has the sulfur atom mainly in the quasiequatorial position. On the other hand, the conformation in which the sulfur is quasiaxial is favored in the 2-NHMe and 2-Et derivatives. We have done ab initio molecular or