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Conformational analysis of the dibenzo [a,g]-quinolizidines by spectroscopic means. II—The use of high resolution 270 MHz proton magnetic resonance

✍ Scribed by D. Tourwé; G. Van Binst; T. Kametani


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
422 KB
Volume
9
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

The 270 MHz ^1^H n.m.r. spectra of some model tetrahydroprotoberberines have been analysed and the dependence of the chemical shifts and the geminal and interbenzylic coupling constants on the conformation examined. Their use for conformational analysis was illustrated on two 8‐methyl substituted epimers.