The solid-state molecular structure and the conformational behaviour in solution of the 12-membered crown dithioether 8-methyl-1,4-dioxa-7,10-dithiacyclododecane-5,12-dione were studied by x-ray crystallography, 1 H and 13 C NMR spectroscopy and molecular mechanics. The conformational rigidity of so
✦ LIBER ✦
Conformational Analysis of the Cyclic Pentadepsipeptide Cyclo(Tro-Aib-Aib-Aib-Aib) in the Solid State and in Solution
✍ Scribed by Kristian N. Koch; Gudrun Hopp; Anthony Linden; Kerstin Moehle; Heinz Heimgartner
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- German
- Weight
- 157 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0018-019X
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Norbornene-supported bis-helical peptides with the general structure NBE(Aib n ) 2 (NBE: 2,3-trans-norbornene dicarbonyl unit; Aib: ␣,␣Ј-dimethyl glycine unit; n ϭ 4,5) have been synthesized and examined for self-assembly preferences in the solid state. An x-ray study has revealed a phenomenon of Ja