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Conformational analysis of some acyclic systems by nuclear magnetic resonance spectroscopy

✍ Scribed by Fritz Schweinsberg; James G. Traynham

Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
207 KB
Volume
11
Category
Article
ISSN
0040-4039

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✦ Synopsis

1n connection with another study,' we prepared some 1,2-dihalo-, 1,3-dihalo-, and 1,2,3trihalo-2,3-dimethylbutanes (I-III, X = Cl or Br). The nuclear magnetic resonance (nmr) spectra of these compounds reveal a surprising degree of conformational preference about C-C single bonds, such a preference, in fact, that the spectra are those one would expect with single conformations for each compound. We believe that some of the features of the conformational analysis of these compounds are of general interest.

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