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Conformational analysis of protected norvaline oligopeptides by high resolution proton magnetic resonance

โœ Scribed by Pysh, E. S.; Toniolo, C.

Book ID
126413635
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
992 KB
Volume
99
Category
Article
ISSN
0002-7863

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The proton magnetic resonance spectrum of thyrotropin releasing factor (TRF) in solution in deuterium oxide and deuterated dimethylsulfoxide (DMSO-d6) has been analyzed. Two forms differing in cis-trans isomerism about the His-Pro peptide bond are observed. From the temperature dependence of chemica