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Conformational analysis of N-acylazabicyclooctanes

✍ Scribed by P. Sohár; I. Pelczer; I. Váczi; A. Tombor; G. Matolcsy

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
940 KB
Volume
23
Category
Article
ISSN
0749-1581

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✦ Synopsis

N-

Acyl derivatives of 1,3,3-trimethyl-6-azabicyclo[3.2.l]octane were synthesized as compounds with potential pesticidal activity. The conformation of the starting compound and the substituent dependence of the amide rotamers of the acyl derivatives were studied by "H and 13C NMR spectroscopy, making use of solvent effects (ASIS) and DR, DNOE and DEPT measurements. , isomers. To establish the stereoisomerism of the rotamers, and to reveal the conformational relation-I 3 ~N H b. " N-C \ X=0(2-9) X=S(lO) 2 R:CH, 7 R:p-OMe-Ph 3 R:CHzCI

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