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Conformational analysis of linear peptides. 3. Temperature dependence of NH chemical shifts in chloroform

✍ Scribed by Stevens, E. S.; Sugawara, N.; Bonora, G. M.; Toniolo, C.


Book ID
120226718
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
442 KB
Volume
102
Category
Article
ISSN
0002-7863

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0 NMR spectra of 1,3-dioxa-2-silacyclooctanes have been studied. The 1 7 0 NMR signal of derivatives existing in the crown conformation is shifted downfield by 7-10 ppm relative to derivatives existing predominantly in conformations belonging to the boat-chair family. This shift is assumed to be due