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Conformational analysis of ethanethiol and 2-propanethiol

✍ Scribed by Don Smith; J. Paul Devlin; Donald W. Scott


Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
551 KB
Volume
25
Category
Article
ISSN
0022-2852

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Kinetic studies on the reactions of 3-is
✍ John O. Morley; A. Jayne Oliver Kapur; Michael H. Charlton 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 265 KB

## Abstract The kinetics of the ring‐opening reactions of the 3‐isothiazolones (**1a–d**) with aqueous 2‐methyl‐2‐propanethiol has been explored at pH 4. The results strongly suggest that the reaction is second order in thiol and third order overall. Extrapolation of the kinetic data gives third‐or