Methyl 2-acetamido-4-amino-2,4,6-trideoxy-3-0-(~-D-galactopyranosyl-uronit acid)-cY-D-galactopyranoside has been synthesised. The parent disaccharide is a structural element of the capsular polysaccharide antigen of Streptococcus pneumoniae type 1.
✦ LIBER ✦
Conformational analysis of a disaccharide fragment of the polysaccharide antigen of Streptococcus pneumoniae type 1 using n.m.r. spectroscopy and HSEA calculations
✍ Scribed by Klaus Bock; Hans Lönn; Thomas Peters
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 290 KB
- Volume
- 198
- Category
- Article
- ISSN
- 0008-6215
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The 1H-n.m.r. spectra of the Streptococcus pneumoniae type 9V (S68 in American nomenclature) capsular polysaccharide (PS) and its O-deacetylated derivative [which is structurally identical to the S. pneumoniae type 9A (S33) PS] were assigned using COSY, relayed-COSY, and 2D-NOESY experiments. The po