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Conformation studies of aerosol-OT in reverse micelles using phase sensitive double quantum COSY NMR spectroscopy

✍ Scribed by Manoj Varshney; Amarnath Maitra


Book ID
103967078
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
297 KB
Volume
96
Category
Article
ISSN
0927-7757

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✦ Synopsis


The conformational changes of the aerosol-OT (AOT) molecule have been established from proton proton coupling constant measurements of the sulphosuccinic part of the molecule. The coupling constant values have been measured directly from the contour plots of the phase sensitive double quantum COSY spectrum. It has been concluded that rotational isomerism exists in the AOT molecule, and the composition of the rotamers in the reverse micelles depends on the water content in the droplets.