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Conformation-reactivity relationship for pyridoxal Schiff's bases. Rates of racemization and α-hydrogen exchange of the pyridoxal Schiff's bases of amino acids

✍ Scribed by Tsai, Ming-Daw; Weintraub, Herschel J. R.; Byrn, Stephen R.; Chang, Ching-Jer; Floss, Heinz G.


Book ID
127384427
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
756 KB
Volume
17
Category
Article
ISSN
0006-2960

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General method for the synthesis of N-me
✍ Jason J. Chruma; Dalibor Sames; Robin Polt 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 127 KB

## N-methyl amino acids, including L-abrine, and N-alkyl amino esters, were synthesized by reductive amination of O'Donnell's Schiff base amino esters with NaBH3CN and formaldehyde, or the appropriate aldehyde in CH3CN or THF in good to excellent yields, and with high purity.