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Conformation of the oligonucleotide d(AAAAAATTTTTT)2 by two-dimensional nuclear overhauser effect spectroscopy and its relevance to poly(dA) · poly(dT)

✍ Scribed by Siddhartha Roy; Babul Borah; Gerald Zon; Jack S. Cohen


Publisher
Wiley (John Wiley & Sons)
Year
1987
Tongue
English
Weight
559 KB
Volume
26
Category
Article
ISSN
0006-3525

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✦ Synopsis


Maryhnd20892

synopsis Conformational analysis from the pattern and intensities of cross-peaks in the two-dimensional nuclear Overhauser effect proton nmr spectra of the homopolymer, poly(dA) . poly(dT), and the analogous oligomer, d(AAAAAAITITIT),, indicate that they both exist in the B-conformation. The conformation of the ApT/TpA junction in the oligomer is significantly different from the rest of the base pairs.