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Conformation of the cyclohexane-1.4-dione molecule in an addition compound

✍ Scribed by P. Groth; O. Hassel


Book ID
104223470
Publisher
Elsevier Science
Year
1964
Tongue
French
Weight
116 KB
Volume
5
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Conformation, in solution, of c-4-t-buty
✍ Muthiah Manoharan; Ernest L. Eliel πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 French βš– 137 KB

Although the hydrochloride of c-4-t-butyl-l-phenyl-c-l-(N-piperidyl)cyclohexane crystallizes in the conformation with axial-t-butyl, it exists as an almost equimolar mixture of the two chair conformers in CD-Cl\_ solution. -The nosition of eauilibrium allows one to calculate AG:-Bu as -4.9 kcal/mol.

The Condensation of Cyclic Aminoketones,
✍ Daniel Berney πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 German βš– 194 KB

## Abstract The title condensations gave respectively: __gem__‐bisarylated cyclic amines **3a–k** or monoarylated unsaturated cyclic amines **4a–g**, 1,3‐bisarylated cyclohexadienes **6a**, **6b**, the condensed bicyclo [2,2,2]‐octane **8**. In addition the aromatic ketone **9** gave the fluorenone