Conformation of the cyclohexane-1.4-dione molecule in an addition compound
β Scribed by P. Groth; O. Hassel
- Book ID
- 104223470
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- French
- Weight
- 116 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Although the hydrochloride of c-4-t-butyl-l-phenyl-c-l-(N-piperidyl)cyclohexane crystallizes in the conformation with axial-t-butyl, it exists as an almost equimolar mixture of the two chair conformers in CD-Cl\_ solution. -The nosition of eauilibrium allows one to calculate AG:-Bu as -4.9 kcal/mol.
## Abstract The title condensations gave respectively: __gem__βbisarylated cyclic amines **3aβk** or monoarylated unsaturated cyclic amines **4aβg**, 1,3βbisarylated cyclohexadienes **6a**, **6b**, the condensed bicyclo [2,2,2]βoctane **8**. In addition the aromatic ketone **9** gave the fluorenone