Conformation of Poly(ethylene oxide)−Hydroxybenzene Molecular Complexes Studied by Solid-State NMR
✍ Scribed by Harris, D. J.; Bonagamba, T. J.; Hong, M.; Schmidt-Rohr, K.
- Book ID
- 126422733
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 232 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0024-9297
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## Abstract The change in the conformation of the flexible OCH~2~CH~2~CH~2~O segment of poly(trimethylene terephthalate) (PTT) monofilament caused by drawing was investigated by means of the γ‐__gauche__ effect on the ^13^C solid‐state NMR chemical shift of the internal methylene carbon, combin
H-, 13C-, 23Na-solid state NMR measurements have been used to characterise the morphology and the dynamics of several NaSCN-PEO mixtures. Selective 13C-MAS experiments allowed to determine the composition of the (PEO)nINaSCN samples in terms of the different phases present, as well as the real stoic