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Conformation of Organophosphorus Compounds. II. Proton Magnetic Resonance Studies of Some Phosphites, Phosphonites, Phosphates, Phosphonates and Additional Phosphinates

โœ Scribed by Siddall, T. H.; Prohaska, C. A.


Book ID
127049464
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
862 KB
Volume
84
Category
Article
ISSN
0002-7863

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The organothio-bridged derivatives of ir
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The anti-syn interconversion rate of (p-Buts),-Fe,(CO), is about one thousand times faster than that of the other alkyl and aryl derivatives and becomes fast in the NMR time scale at temperatures above 90 'C. The coalescence temperature of the But signals is lowered by substitution of a carbonyl gro