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Conformation of open-chain compounds. Part 3. Carbon-halogen stretching frequencies and conformation of some vicinal dihalides

✍ Scribed by C. Altona; H.J. Hageman

Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 387 KB
Volume: 88
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19690880107

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Recently, the conformational equilibria in some vicinal dihslcgencalkanes (see Fig.1) have been studied (2,3) by means of dipole moments in benzene and in carbon tetrachlcride solution at 25'c. From the experimental equilibrium constants the gauche interaction FIG.l. The conformers of vicinal dihalc