Conformation of non-aromatic ring compounds. Part 61 Conformational equilibrium in trans-2-halogenocyclohexanols
β Scribed by H. R. Buys; H. J. A. de Vries; H. J. Hageman; C. Altona
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 516 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0165-0513
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In a previous paper (2) the conformation81 features of six 2-alkoxytetrahydropyrans (Fig. 1, R = Me, Et, n-Pr, i-Pr, n-Bu, t-Bu) were discussed on the baais of dipole moment and NMR results. The main conclusions concerning the conformational equilibrium and the
## Abstract The dipole moments and vicinal coupling constants of __cis__β2βbromoβ, __cis__β2βchloroβ and __cis__β2βfluoroβ4β__t__βbutylcyclohexanone have been determined in several solvents, in order to investigate the conformational homogeneity of these compounds. The dipole moments show a small s