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Conformation of non-aromatic ring compounds. Part 61 Conformational equilibrium in trans-2-halogenocyclohexanols

✍ Scribed by H. R. Buys; H. J. A. de Vries; H. J. Hageman; C. Altona


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
516 KB
Volume
89
Category
Article
ISSN
0165-0513

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Conformation of non-aromatic ring compou
✍ A.J. de Hoog; H.R. Buys πŸ“‚ Article πŸ“… 1969 πŸ› Elsevier Science 🌐 French βš– 183 KB

In a previous paper (2) the conformation81 features of six 2-alkoxytetrahydropyrans (Fig. 1, R = Me, Et, n-Pr, i-Pr, n-Bu, t-Bu) were discussed on the baais of dipole moment and NMR results. The main conclusions concerning the conformational equilibrium and the

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✍ H. R. Buys; M. T. Giesen; E. Havinga πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 302 KB

## Abstract The dipole moments and vicinal coupling constants of __cis__‐2‐bromo‐, __cis__‐2‐chloro‐ and __cis__‐2‐fluoro‐4‐__t__‐butylcyclohexanone have been determined in several solvents, in order to investigate the conformational homogeneity of these compounds. The dipole moments show a small s